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# The Physics of Diving – Scuba Gas Laws

## A concise explanation of the critical scuba gas laws for divers

by Andy Davis

Scuba diving is all about getting gas into your body while you are underwater. What complicates scuba diving is the way gasses behaves at depth, under pressure, in your body and in your equipment.

To dive safely and effectively, you need to understand all the behaviour of these gasses intuitively and how they affect the techniques and practice of scuba diving.

As part of your scuba certification, you will have come to understand certain principles of physics, in particular, the scuba gas laws which apply to diving. When you understand the scuba gas laws all the intricacies of nitrogen management, off-gassing and even the process of inflating and deflating your BCD will make more sense.

## Scuba Gas Laws – Boyle’s Law

Boyle’s Law is named after Robert Boyle (1627-1691). Edme Mariotte (1620-1684), a French physicist, discovered the law independently at roughly the same time, so this law is often known as Mariotte’s or Boyle Mariotte’s law. During scuba diving classes the law is usually called Boyle’s Law. Boyle’s law relates the volume and pressure of a gas held at a constant temperature. Boyle’s law is:

PV = k

Where:

• P is the pressure of gas,
• V is the volume of gas
• k is a constant.
• The constant k does not need to be known to understand the relationship between P and V.

Boyle’s law basically says this:

• When you increase the pressure the volume decreases.
• When you increase the volume the pressure decreases.

This Law is often applied to demonstrate what happens during ascent and descent and how it compensates the pressure in the BCD, lungs, mask and anywhere else that air is contained. As you descend, pressure increases. As pressure increases volume decreases, so the same amount of air takes up less space.

Because of this, as you descend you will notice that your BCD “deflates”. It is not losing air, it is compressing the same air into a smaller volume. You may also notice other effects of airspaces being compressed – wet suits fit less snugly (if you are wearing a thick neoprene suit this is even more apparent) and the airspace behind ears becomes decompressed. When equalizing you need to let more air into your Eustachian tubes to compensate for the reduction in volume.

Likewise, as you ascend pressure decreases and volume increases.

A full BCD at depth will become fuller as you ascend – that is why you must release air from your BCD as you ascend. More importantly, it is important to exhale from your lungs as you ascend. If you hold your breath while ascending the air in your lungs expands beyond capacity, which can cause painful internal injuries.

## Scuba Gas Laws – Charles’ Law

Charles’ Law states the relationship between temperature and volume of a gas at a constant pressure.

T/V = k

Where:

• T is the temperature of the gas, V is the volume and k is a constant.

In a nutshell, Charles’ law says that cooling a gas decreases its volume. If the volume remains fixed then the pressure must decrease. A suitable example of this phenomenon is a scuba tank bursting because it is left in the trunk of a hot car in the tropical sun (temperature rises, the volume is constant and pressure increases).

Likewise, as you ascend pressure decreases and volume increases. A full BCD at depth will become fuller as you ascend – that is why you must release air from your BCD as you ascend.

More importantly, it is important to exhale from your lungs as you ascend. If you hold your breath while ascending the air in your lungs expands beyond capacity, which can cause painful internal injuries.

## Scuba Gas Laws – Henry’s Law

Henry’s Law is named for William Henry, who in 1801 stated that the mass of a gas which dissolves in a volume of liquid is proportional to the pressure of the gas.

e^P = e^{kC}

Taking the natural logarithm of this equation we get the more common version:

P=KC

Where:

• P = the partial pressure of the gas solute,
• C is the concentration of the gas
• K = the Henry’s Law constant.

To a scuba diver, Henry’s Law tells us that at higher pressure our bodies will absorb more gasses. At great depths, the amount of nitrogen (and other gases) absorbed into our blood and tissue is greater than the amount absorbed at shallow depths.

That is why a diver going to 100′ has a greater risk of decompression illness than a diver who dives only 30 feet. Since the shallow diver has absorbed less gas, it is less likely to come out of solution in the body.

## Scuba Gas Laws – Dalton’s Law of Partial Pressures

Dalton’s Law is named for John Dalton, who stated the law in 1801. The law states that the pressure exerted by a mixture of gases is equal to the sum of the pressures which would be exerted by the gases individually.

Dalton’s Law states that:

The total pressure exerted by a mixture of gases is equal to the sum of the pressures that would be exerted by each of the gases if it alone were present and occupied by the total volume.

In other words, as pressure increases, partial pressure increases and vice versa.

The mathematical formula describing Dalton’s Law is:

Ptotal = Pp1 + Pp2 + Ppn

where:

• Ptotal = total pressure of the gas
• Pp1 = partial pressure of gas component 1
• Pp2 = partial pressure of gas component 2
• Ppn = partial pressure of other gas components

Dalton’s discovery was all gases tend to compress similarly. If you have a mixture of nitrogen and oxygen and you add 100lbs of pressure both the nitrogen and oxygen will compress equally.

Dalton’s Law specifically deals with partial pressures. These are relevant to a number of issues in diving, including decompression, gas toxicity, use of breathing mixtures other than air, and maximum operating depths for diving. This article focuses on gas toxicity.

## Air Mixtures and Partial Pressures

The air compressed into a scuba cylinder is for all practical purposes a gas mixture comprised of 79 % nitrogen molecules (N2) and 21 % oxygen molecules (O2).

While these gas percentages define the ratios between the number of gas molecules in the mixture, it is the partial pressures of each that is responsible for the physiological effects of the individual gas.

As the diver descends, they breathe increasingly more dense air because the regulator delivers air at a pressure to match the external (ambient) water pressure. Thus, Dalton’s Law dictates that the diver is breathing correspondingly more oxygen and nitrogen molecules, per breath, the deeper they go.

The partial pressure of any given gas within the breathing mixture can be calculated by the following formula:

## Scuba Gas Laws – Oxygen Toxicity

It is the partial pressures of each that is responsible for the physiological effects of the individual gas. Increase partial pressure of nitrogen can cause narcosis. The increased partial pressure of oxygen can cause toxicity (convulsions and unconsciousness).

As we have seen; the deeper a diver goes, the higher the partial pressures exhibited by the component gases in their breathing gas.

Breathing oxygen is vital to sustain life, but at higher partial pressures, oxygen becomes toxic. The maximum O2 partial pressure a human nervous system can safely stand is 1.6 ata. (PADI recommend 1.4 ata PPO2 for normal diving).

Should a diver lose track of their depth and pass below the safe Maximum Operating Depth (MOD) for their breathing gas (air or nitrox), then they would become susceptible to oxygen toxicity.

Andy Davis is a RAID, PADI TecRec, ANDI, BSAC and SSI qualified independent technical diving instructor who specializes in teaching advanced sidemount, trimix and wreck exploration diving courses across South East Asia.  Currently residing in ‘wreck diving heaven’ at Subic Bay, Philippines, he has amassed more than 9000 open circuit and CCR dives over 27 years of diving across the globe.

Andy has published many magazine articles on technical diving, has written course materials for dive training agency syllabus, tests and reviews diving gear for major manufacturers and consults with the Philippines Underwater Archaeology Society.

He is currently writing a series of books to be published on advanced diving topics.  Prior to becoming a professional technical diving educator in 2006, Andy was a commissioned officer in the Royal Air Force and has served in Iraq, Afghanistan, Belize and Cyprus.

Originally posted 2018-03-07 23:56:57.

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